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ABSTRACT: Calcium-containing minerals are key modelsystems for investigating fundamental principles of nucleationand mineral formation both experimentally and by simulation. Due to the rare event character of nucleation, the different dimensions of pre- and postnucleation stages and the possible relevance of nonclassical nucleation pathways, such investigations require advanced sampling techniques and simulationmodels on a range of resolution levels. To this end, we have developed coarse-grained (CG) models for calcium carbonate.We present a strategy to devise CG parameters, including nonbonded angular-dependent terms such that the model correctly represents the calcite phase along with properties of the constituents in solution. We show how the CG interactions affect the crystallization pathways by stabilizing different intermediates, spanning a wide range of degrees of crystallinity and water content. This will allow us to investigate contributionsto crystallization transitions and link them to experimentally observed nonclassical crystallization intermediates.